Organometallic Compounds

Organometallic compounds contain direct bonds between carbon atoms and metal atoms/ions and play roles as homogeneous catalysts and stoichiometric reagents in reactions; available in various chemical compositions, quantities, purities, and reagent grades.

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Diisobutylaluminium hydride, 1.2M (20 wt%) solution in toluene, AcroSeal™, Thermo Scientific Chemicals

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Boiling Point	110.0°C
Linear Formula	[(CH₃)₂CHCH₂]₂AIH
Molecular Weight (g/mol)	142.22
Physical Form	Solution
Chemical Name or Material	Diisobutylaluminium hydride
Merck Index	15, 3212
Density	0.8480g/mL
Fieser	01,260; 02,140; 03,101; 04,158; 05,224; 06,198; 07,111; 08,173; 09,171; 10,149; 11,185; 12,191; 13,115; 14,138; 15,137; 16,27; 17,123
CAS	108-88-3
Health Hazard 3	GHS P Statement IF SWALLOWED: rinse mouth. Do NOT induce vomiting. Wear eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,if present and easy to do. Continue rinsi
MDL Number	MFCD00008928
Health Hazard 2	GHS H Statement Causes severe skin burns and eye damage. May be fatal if swallowed and enters airways. May cause damage to organs through prolonged or repeated exposure. Suspected of damaging the unborn child. May cause dro
Solubility Information	Solubility in water: reacts violently. Other solubilities: miscible with saturated aliphatic and aromatic,hydrocarbons
Flash Point	4°C
Health Hazard 1	GHS Signal Word: Danger
Synonym	DIBAL-H
Beilstein	04, IV, 4400
Molecular Formula	C₈H₁₉Al
EINECS Number	214-729-9
Formula Weight	142.22
Specific Gravity	0.848

Lithium bis(trimethylsilyl)amide, 1M solution in THF, AcroSeal™, Thermo Scientific Chemicals

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Boiling Point	65.0°C
Linear Formula	((CH₃)₃Si)₂NLi
Molecular Weight (g/mol)	167.33
Chemical Name or Material	Lithium bis(trimethylsilyl)amide
SMILES	[Li+].C[Si](C)(C)[N-][Si](C)(C)C
InChI Key	YNESATAKKCNGOF-UHFFFAOYSA-N
Density	0.9000g/mL
PubChem CID	2733832
Fieser	04,296; 05,393; 07,197; 12,280; 13,165; 14,194
CAS	109-99-9
Health Hazard 3	GHS P Statement Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Wear protective gloves/protective clothing/eye p
Health Hazard 2	GHS H Statement Highly flammable liquid and vapor. Causes severe skin burns and eye damage. May cause respiratory irritation. Suspected of causing cancer. May form explosive peroxides. Reacts violently with water.<br/
Solubility Information	Solubility in water: reacts.
Flash Point	−21°C
Health Hazard 1	GHS Signal Word: Danger
Synonym	lithium bis trimethylsilyl amide,lithium hexamethyldisilazide,lihmds,lhmds,hexamethyldisilazane lithium salt,unii-rc4n1i108m,lithiumbis trimethylsilyl amide,lithium bis trimethylsilyl azanide,lithium hexamethyldisilazane,lithium bis-trimethylsilyl amide
IUPAC Name	lithium;bis(trimethylsilyl)azanide
Molecular Formula	C₆H₁₈LiNSi₂
EINECS Number	223-725-6
Formula Weight	167.33
Specific Gravity	0.9

Diisobutylaluminium hydride, 1M solution in hexane, AcroSeal™, Thermo Scientific Chemicals

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Linear Formula	[(CH₃)₂CHCH₂]₂AlH
Molecular Weight (g/mol)	142.22
Physical Form	Solution
Chemical Name or Material	Diisobutylaluminium hydride
Merck Index	15, 3212
Density	0.7010g/mL
Name Note	1M Solution in Hexane
Fieser	01,260; 02,140; 03,101; 04,158; 05,224; 06,198; 07,111; 08,173; 09,171; 10,149; 11,185; 12,191; 13,115; 14,138; 15,137; 16,27; 17,123
CAS	110-54-3
Health Hazard 3	GHS P Statement IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,if present and easy to do. Continue rinsing. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective g
MDL Number	MFCD00008928
Health Hazard 2	GHS H Statement May be fatal if swallowed and enters airways. Toxic to aquatic life with long lasting effects. Causes severe skin burns and eye damage. May cause drowsiness or dizziness. May cause damage to organs through p
Solubility Information	Solubility in water: reacts
Flash Point	−23°C
Health Hazard 1	GHS Signal Word: Danger
Synonym	DIBAL-H
Beilstein	04, IV, 4400
Molecular Formula	C₈H₁₉Al
EINECS Number	214-729-9
Formula Weight	142.22
Specific Gravity	0.701
Melting Point	-70.0°C

Lithium bis(trimethylsilyl)amide, 1M solution in THF/Ethylbenzene, AcroSeal™, Thermo Scientific Chemicals

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Molecular Weight (g/mol)	167.33
Color	Yellow to Brown
Physical Form	Turbid Solution
Chemical Name or Material	Lithium bis(trimethylsilyl)amide
SMILES	[Li+].C[Si](C)(C)[N-][Si](C)(C)C
InChI Key	YNESATAKKCNGOF-UHFFFAOYSA-N
Density	0.8900g/mL
PubChem CID	2733832
Name Note	1M Solution in THF/Ethylbenzene
Percent Purity	18 to 22% active base (as LiNSi)
Fieser	04,296; 05,393; 07,197; 12,280; 13,165; 14,194
CAS	100-41-4
Health Hazard 3	GHS P Statement Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: rinse mouth. Do NOT induce vomiting. IF ON SKIN (or ha
MDL Number	MFCD00008261
Health Hazard 2	GHS H Statement Causes severe skin burns and eye damage. May cause respiratory irritation. Highly flammable liquid and vapor. Suspected of causing cancer. Reacts violently with water. May form explosive peroxides.<br/
Solubility Information	Solubility in water: decomposes
Flash Point	−21°C
Health Hazard 1	GHS Signal Word: Danger
Synonym	lithium bis trimethylsilyl amide,lithium hexamethyldisilazide,lihmds,lhmds,hexamethyldisilazane lithium salt,unii-rc4n1i108m,lithiumbis trimethylsilyl amide,lithium bis trimethylsilyl azanide,lithium hexamethyldisilazane,lithium bis-trimethylsilyl amide
TSCA	TSCA
IUPAC Name	lithium;bis(trimethylsilyl)azanide
Molecular Formula	C₆H₁₈LiNSi₂
EINECS Number	223-725-6
Formula Weight	167.33
Specific Gravity	0.89

Hexamethyldisilazane, 98+%, Thermo Scientific Chemicals

CAS: 999-97-3 Molecular Formula: C6H19NSi2 Molecular Weight (g/mol): 161.395 MDL Number: MFCD00008259 InChI Key: FFUAGWLWBBFQJT-UHFFFAOYSA-N Synonym: hexamethyldisilazane,bis trimethylsilyl amine,hmds,1,1,1,3,3,3-hexamethyldisilazane,hexamethylsilazane,silanamine, 1,1,1-trimethyl-n-trimethylsilyl,tri-sil,1,1,1-trimethyl-n-trimethylsilyl silanamine,hexamethyldisilizane,disilazane, 1,1,1,3,3,3-hexamethyl PubChem CID: 13838 ChEBI: CHEBI:85068 IUPAC Name: [dimethyl-(trimethylsilylamino)silyl]methane SMILES: C[Si](C)(C)N[Si](C)(C)C

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PubChem CID	13838
CAS	999-97-3
Molecular Weight (g/mol)	161.395
ChEBI	CHEBI:85068
MDL Number	MFCD00008259
SMILES	C[Si](C)(C)N[Si](C)(C)C
Synonym	hexamethyldisilazane,bis trimethylsilyl amine,hmds,1,1,1,3,3,3-hexamethyldisilazane,hexamethylsilazane,silanamine, 1,1,1-trimethyl-n-trimethylsilyl,tri-sil,1,1,1-trimethyl-n-trimethylsilyl silanamine,hexamethyldisilizane,disilazane, 1,1,1,3,3,3-hexamethyl
IUPAC Name	[dimethyl-(trimethylsilylamino)silyl]methane
InChI Key	FFUAGWLWBBFQJT-UHFFFAOYSA-N
Molecular Formula	C6H19NSi2

Hexamethyldisiloxane, 98+%, Thermo Scientific Chemicals

CAS: 107-46-0 InChI Key: UQEAIHBTYFGYIE-UHFFFAOYSA-N Synonym: hexamethyldisiloxane,disiloxane, hexamethyl,hexamethyl disiloxane,oxybis trimethylsilane,fluka ag,hmdso,bis trimethylsilyl ether,belsil dm 0.65,bis trimethylsilyl oxide PubChem CID: 24764 ChEBI: CHEBI:78002 IUPAC Name: trimethyl(trimethylsilyloxy)silane SMILES: C[Si](C)(C)O[Si](C)(C)C

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PubChem CID	24764
CAS	107-46-0
ChEBI	CHEBI:78002
SMILES	C[Si](C)(C)O[Si](C)(C)C
Synonym	hexamethyldisiloxane,disiloxane, hexamethyl,hexamethyl disiloxane,oxybis trimethylsilane,fluka ag,hmdso,bis trimethylsilyl ether,belsil dm 0.65,bis trimethylsilyl oxide
IUPAC Name	trimethyl(trimethylsilyloxy)silane
InChI Key	UQEAIHBTYFGYIE-UHFFFAOYSA-N

Chlorotrimethylsilane, 98%, Thermo Scientific Chemicals

CAS: 75-77-4 Molecular Formula: C₃H₉ClSi Molecular Weight (g/mol): 108.64 MDL Number: MFCD00000502 InChI Key: IJOOHPMOJXWVHK-UHFFFAOYSA-N Synonym: trimethylchlorosilane,trimethylsilyl chloride,silane, chlorotrimethyl,trimethyl chlorosilane,monochlorotrimethylsilicon,tmcs,chloro trimethyl silane,silane, trimethylchloro,silicane, chlorotrimethyl,tmscl PubChem CID: 6397 ChEBI: CHEBI:85069 IUPAC Name: chloro(trimethyl)silane SMILES: C[Si](C)(C)Cl

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PubChem CID	6397
CAS	75-77-4
Molecular Weight (g/mol)	108.64
ChEBI	CHEBI:85069
MDL Number	MFCD00000502
SMILES	C[Si](C)(C)Cl
Synonym	trimethylchlorosilane,trimethylsilyl chloride,silane, chlorotrimethyl,trimethyl chlorosilane,monochlorotrimethylsilicon,tmcs,chloro trimethyl silane,silane, trimethylchloro,silicane, chlorotrimethyl,tmscl
IUPAC Name	chloro(trimethyl)silane
InChI Key	IJOOHPMOJXWVHK-UHFFFAOYSA-N
Molecular Formula	C₃H₉ClSi

Sodium tetraethylborate, 97%, pure, Thermo Scientific Chemicals

CAS: 15523-24-7 Molecular Formula: C₈H₂₀BNa Molecular Weight (g/mol): 150.04 MDL Number: MFCD00061547 InChI Key: SZSBMTRYJRHYNI-UHFFFAOYSA-N Synonym: sodium tetraethylborate,sodium tetraethylboranuide,borate 1-,tetraethyl-, sodium 1:1,sodium tetraethylborate 1-,et4bna,sodiotetraethylboron v,borate 1-, tetraethyl-, sodium,sodium tetraethylborate 1g PubChem CID: 23681030 IUPAC Name: sodium;tetraethylboranuide SMILES: [B-](CC)(CC)(CC)CC.[Na+]

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PubChem CID	23681030
CAS	15523-24-7
Molecular Weight (g/mol)	150.04
MDL Number	MFCD00061547
SMILES	[B-](CC)(CC)(CC)CC.[Na+]
Synonym	sodium tetraethylborate,sodium tetraethylboranuide,borate 1-,tetraethyl-, sodium 1:1,sodium tetraethylborate 1-,et4bna,sodiotetraethylboron v,borate 1-, tetraethyl-, sodium,sodium tetraethylborate 1g
IUPAC Name	sodium;tetraethylboranuide
InChI Key	SZSBMTRYJRHYNI-UHFFFAOYSA-N
Molecular Formula	C₈H₂₀BNa

Dichlorodimethylsilane, 99+%, AcroSeal™, Thermo Scientific Chemicals

CAS: 75-78-5 Molecular Formula: C₂H₆Cl₂Si Molecular Weight (g/mol): 129.06 MDL Number: MFCD00000491 InChI Key: LIKFHECYJZWXFJ-UHFFFAOYSA-N Synonym: dimethyldichlorosilane,silane, dichlorodimethyl,dichloro dimethyl silane,inerton aw-dmcs,dichlorodimethylsilicon,dimethyl-dichlorsilan,inerton dw-dmc,repel-silan,dimethylsilane dichloride,dimethyl dichlorosilane PubChem CID: 6398 IUPAC Name: dichloro(dimethyl)silane SMILES: C[Si](C)(Cl)Cl

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PubChem CID	6398
CAS	75-78-5
Molecular Weight (g/mol)	129.06
MDL Number	MFCD00000491
SMILES	C[Si](C)(Cl)Cl
Synonym	dimethyldichlorosilane,silane, dichlorodimethyl,dichloro dimethyl silane,inerton aw-dmcs,dichlorodimethylsilicon,dimethyl-dichlorsilan,inerton dw-dmc,repel-silan,dimethylsilane dichloride,dimethyl dichlorosilane
IUPAC Name	dichloro(dimethyl)silane
InChI Key	LIKFHECYJZWXFJ-UHFFFAOYSA-N
Molecular Formula	C₂H₆Cl₂Si

N,O-Bis(trimethylsilyl)trifluoroacetamide, 98+%, Thermo Scientific Chemicals

CAS: 25561-30-2 Molecular Formula: C₈H₁₈F₃NOSi₂ Molecular Weight (g/mol): 257.39 MDL Number: MFCD00008269 InChI Key: XCOBLONWWXQEBS-GHXNOFRVSA-N Synonym: bstfa,n,o-bis trimethylsilyl trifluoroacetamide,acetamide, 2,2,2-trifluoro-o,n-bis trimethylsilyl,trimethylsilyl 2,2,2-trifluoro-n-trimethylsilyl acetimidate,trimethylsilyl 2,2,2-trifluoro-n-trimethylsilyl ethanimidate,trimethylsilyl 1z-2,2,2-trifluoro-n-z-trimethylsilyl ethanimidoate #,n,o-bis trimethylsilyl trifluoroacetamide bstfa,trimethylsilyl 2,2,2-trifluoro-n-trimethylsilyl ethanecarboximidate PubChem CID: 9601896 IUPAC Name: trimethylsilyl (1Z)-2,2,2-trifluoro-N-trimethylsilylethanimidate SMILES: C[Si](C)(C)N=C(C(F)(F)F)O[Si](C)(C)C

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PubChem CID	9601896
CAS	25561-30-2
Molecular Weight (g/mol)	257.39
MDL Number	MFCD00008269
SMILES	C[Si](C)(C)N=C(C(F)(F)F)O[Si](C)(C)C
Synonym	bstfa,n,o-bis trimethylsilyl trifluoroacetamide,acetamide, 2,2,2-trifluoro-o,n-bis trimethylsilyl,trimethylsilyl 2,2,2-trifluoro-n-trimethylsilyl acetimidate,trimethylsilyl 2,2,2-trifluoro-n-trimethylsilyl ethanimidate,trimethylsilyl 1z-2,2,2-trifluoro-n-z-trimethylsilyl ethanimidoate #,n,o-bis trimethylsilyl trifluoroacetamide bstfa,trimethylsilyl 2,2,2-trifluoro-n-trimethylsilyl ethanecarboximidate
IUPAC Name	trimethylsilyl (1Z)-2,2,2-trifluoro-N-trimethylsilylethanimidate
InChI Key	XCOBLONWWXQEBS-GHXNOFRVSA-N
Molecular Formula	C₈H₁₈F₃NOSi₂

(3-Aminopropyl)trimethoxysilane, 97%, Thermo Scientific Chemicals

CAS: 13822-56-5 Molecular Formula: C6H17NO3Si Molecular Weight (g/mol): 179.291 MDL Number: MFCD00008206 InChI Key: SJECZPVISLOESU-UHFFFAOYSA-N Synonym: 3-aminopropyltrimethoxysilane,3-aminopropyl trimethoxysilane,3-trimethoxysilyl-1-propanamine,3-trimethoxysilyl propan-1-amine,3-trimethoxysilyl propylamine,1-propanamine, 3-trimethoxysilyl,silane sc 3900,n-trimethoxysilylpropyl amine,propylamine, 3-trimethoxysilyl,unii-7mry0c9sb6 PubChem CID: 83756 IUPAC Name: 3-trimethoxysilylpropan-1-amine SMILES: CO[Si](CCCN)(OC)OC

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PubChem CID	83756
CAS	13822-56-5
Molecular Weight (g/mol)	179.291
MDL Number	MFCD00008206
SMILES	CO[Si](CCCN)(OC)OC
Synonym	3-aminopropyltrimethoxysilane,3-aminopropyl trimethoxysilane,3-trimethoxysilyl-1-propanamine,3-trimethoxysilyl propan-1-amine,3-trimethoxysilyl propylamine,1-propanamine, 3-trimethoxysilyl,silane sc 3900,n-trimethoxysilylpropyl amine,propylamine, 3-trimethoxysilyl,unii-7mry0c9sb6
IUPAC Name	3-trimethoxysilylpropan-1-amine
InChI Key	SJECZPVISLOESU-UHFFFAOYSA-N
Molecular Formula	C6H17NO3Si

Tetraethyl orthosilicate, 98%, Thermo Scientific Chemicals

CAS: 78-10-4 Molecular Formula: C₈H₂₀O₄Si Molecular Weight (g/mol): 208.33 MDL Number: MFCD00009062 InChI Key: BOTDANWDWHJENH-UHFFFAOYSA-N Synonym: tetraethyl orthosilicate,tetraethoxysilane,teos,ethyl silicate,silicon ethoxide,silicon tetraethoxide,silane, tetraethoxy,dynasil a,tetraethoxysilicon,ethyl orthosilicate PubChem CID: 6517 IUPAC Name: tetraethyl silicate SMILES: CCO[Si](OCC)(OCC)OCC

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PubChem CID	6517
CAS	78-10-4
Molecular Weight (g/mol)	208.33
MDL Number	MFCD00009062
SMILES	CCO[Si](OCC)(OCC)OCC
Synonym	tetraethyl orthosilicate,tetraethoxysilane,teos,ethyl silicate,silicon ethoxide,silicon tetraethoxide,silane, tetraethoxy,dynasil a,tetraethoxysilicon,ethyl orthosilicate
IUPAC Name	tetraethyl silicate
InChI Key	BOTDANWDWHJENH-UHFFFAOYSA-N
Molecular Formula	C₈H₂₀O₄Si

tert-Butylchlorodimethylsilane, 98%, Thermo Scientific Chemicals

CAS: 18162-48-6 Molecular Formula: C₆H₁₅ClSi Molecular Weight (g/mol): 150.73 MDL Number: MFCD00000501 InChI Key: BCNZYOJHNLTNEZ-UHFFFAOYSA-N Synonym: tert-butyldimethylsilyl chloride,tert-butyldimethylchlorosilane,t-butyldimethylchlorosilane,tert-butylchlorodimethylsilane,tbdms chloride,tert-butyl chloro dimethylsilane,chloro-tert-butyldimethylsilane,silane, chloro 1,1-dimethylethyl dimethyl,tbscl,t-butyldimethylsilyl chloride PubChem CID: 28928 ChEBI: CHEBI:85071 IUPAC Name: tert-butyl-chloro-dimethylsilane SMILES: CC(C)(C)[Si](C)(C)Cl

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PubChem CID	28928
CAS	18162-48-6
Molecular Weight (g/mol)	150.73
ChEBI	CHEBI:85071
MDL Number	MFCD00000501
SMILES	CC(C)(C)[Si](C)(C)Cl
Synonym	tert-butyldimethylsilyl chloride,tert-butyldimethylchlorosilane,t-butyldimethylchlorosilane,tert-butylchlorodimethylsilane,tbdms chloride,tert-butyl chloro dimethylsilane,chloro-tert-butyldimethylsilane,silane, chloro 1,1-dimethylethyl dimethyl,tbscl,t-butyldimethylsilyl chloride
IUPAC Name	tert-butyl-chloro-dimethylsilane
InChI Key	BCNZYOJHNLTNEZ-UHFFFAOYSA-N
Molecular Formula	C₆H₁₅ClSi

Azidotrimethylsilane, 94%, Thermo Scientific Chemicals

CAS: 4648-54-8 Molecular Formula: C3H9N3Si Molecular Weight (g/mol): 115.21 MDL Number: MFCD00001986 InChI Key: SEDZOYHHAIAQIW-UHFFFAOYSA-N Synonym: trimethylsilyl azide,silane, azidotrimethyl,trimethylsilylazide,azido trimethyl silane,ccris 8048,tms azide,tms-azide,trimethyl silylazide,trimethylsilyl-azide,azido trimethylsilane PubChem CID: 78378 IUPAC Name: azido(trimethyl)silane SMILES: C[Si](C)(C)N=[N+]=[N-]

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PubChem CID	78378
CAS	4648-54-8
Molecular Weight (g/mol)	115.21
MDL Number	MFCD00001986
SMILES	C[Si](C)(C)N=[N+]=[N-]
Synonym	trimethylsilyl azide,silane, azidotrimethyl,trimethylsilylazide,azido trimethyl silane,ccris 8048,tms azide,tms-azide,trimethyl silylazide,trimethylsilyl-azide,azido trimethylsilane
IUPAC Name	azido(trimethyl)silane
InChI Key	SEDZOYHHAIAQIW-UHFFFAOYSA-N
Molecular Formula	C3H9N3Si

Iodotrimethylsilane, 95-97%, stabilized, Thermo Scientific Chemicals

CAS: 16029-98-4 Molecular Formula: C₃H₉ISi Molecular Weight (g/mol): 200.1 MDL Number: MFCD00001028 InChI Key: CSRZQMIRAZTJOY-UHFFFAOYSA-N Synonym: trimethylsilyl iodide,trimethyliodosilane,silane, iodotrimethyl,iodo trimethyl silane,trimethylsilyliodide,tms-iodide,iodotrimethysilane,iodotrimetylsilane,tms iodide,iodo trimethylsilane PubChem CID: 85247 IUPAC Name: iodo(trimethyl)silane SMILES: C[Si](C)(C)I

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PubChem CID	85247
CAS	16029-98-4
Molecular Weight (g/mol)	200.1
MDL Number	MFCD00001028
SMILES	C[Si](C)(C)I
Synonym	trimethylsilyl iodide,trimethyliodosilane,silane, iodotrimethyl,iodo trimethyl silane,trimethylsilyliodide,tms-iodide,iodotrimethysilane,iodotrimetylsilane,tms iodide,iodo trimethylsilane
IUPAC Name	iodo(trimethyl)silane
InChI Key	CSRZQMIRAZTJOY-UHFFFAOYSA-N
Molecular Formula	C₃H₉ISi

Organometallic Compounds

Organometallic Compounds

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