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  6. 1-(Triisopropylsilyl)pyrrole, 95%, Thermo Scientific Chemicals

1-(Triisopropylsilyl)pyrrole, 95%, Thermo Scientific Chemicals

Product Code. 11397936
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Quantity:
1 g
5 g
25 g
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Description

1-(Triisopropylsilyl)pyrrole may be employed as reagent in perfluoroalkylation and Vilsmeier formylation reactions. It may be used in the preparation of ethyl 2-(2,4-dinitrophenylhydrazono]-3-[ 1-(triisopropylsily1)-pyrrol-2-yflpropanoate; heterocyclic base, 3-nitropyrrole and 3-nitropyrrole, required for the synthesis of 1 -(2?-deoxy-β-D-ribofuranosyl)-3-nitropyrrole. It participates in various electrophilic substitution reactions specifically at β-position, via reaction with various electrophilic reagents (Br+, I+,NO2+,etc).

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1-(Triisopropylsilyl)pyrrole may be employed as reagent in perfluoroalkylation and Vilsmeier formylation reactions. It may be used in the preparation of ethyl 2-(2,4-dinitrophenylhydrazono]-3-[ 1-(triisopropylsily1)-pyrrol-2-yflpropanoate; heterocyclic base, 3-nitropyrrole and 3-nitropyrrole, required for the synthesis of 1 -(2′-deoxy-β-D-ribofuranosyl)-3-nitropyrrole. It participates in various electrophilic substitution reactions specifically at β-position, via reaction with various electrophilic reagents (Br+, I+,NO2+,etc).

Solubility
Not miscible in water.

Notes
Moisture sensitive. Incompatible with oxidizing agents.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 87630-35-1
Molecular Formula C13H25NSi
Molecular Weight (g/mol) 223.44
MDL Number MFCD00054932
InChI Key FBQURXLBJJNDBX-UHFFFAOYSA-N
Synonym 1-triisopropylsilyl pyrrole, 1-triisopropylsilyl-1h-pyrrole, n-triisopropylsilylpyrrole, 1h-pyrrole, 1-tris 1-methylethyl silyl, tri propan-2-yl-pyrrol-1-ylsilane, 1-tris propan-2-yl silyl-1h-pyrrole, pubchem9194, 1-triisopropylsilylpyrrole, 1-triisoproylsilyl-pyrrole, acmc-1bkd7
PubChem CID 145136
IUPAC Name tri(propan-2-yl)-pyrrol-1-ylsilane
SMILES CC(C)[Si](C(C)C)(C(C)C)N1C=CC=C1

Specifications

Density 0.904
Boiling Point 78°C (0.4 mmHg)
Flash Point 106°C (222°F)
Refractive Index 1.492
Quantity 5 g
Beilstein 3540663
Sensitivity Moisture sensitive
Solubility Information Not miscible in water.
Formula Weight 223.44
Percent Purity 95%
Chemical Name or Material 1-(Triisopropylsilyl)pyrrole
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