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1H-Benzotriazol-1-yloxytris(dimethylamino)phosphonium hexafluorophosphate, 98%, Thermo Scientific Chemicals
33.37 EUR - 316.58 EUR
Chemical Identifiers
| CAS | 56602-33-6 |
|---|---|
| Molecular Formula | C12H22F6N6OP2 |
| Molecular Weight (g/mol) | 442.287 |
| MDL Number | MFCD00011948 |
| InChI Key | MGEVGECQZUIPSV-UHFFFAOYSA-N |
| Synonym | bop reagent, 1h-benzo d 1,2,3 triazol-1-yl oxy tris dimethylamino phosphonium hexafluorophosphate v, castro's reagent, bop-reagent, benzotriazol-1-yloxytris dimethylamino-phosphonium hexafluorophosphate, ccris 2602, castros reagent, tri dimethylamino benzotriazol-1-yloxyphosphonium hexafluorophosphate, benzotriazol-1-yloxy tris dimethylamino phosphonium hexafluorophosphate, 1h-benzotriazol-1-yloxytris dimethylamino phosphonium hexafluorophosphate |
| PubChem CID | 151348 |
| IUPAC Name | benzotriazol-1-yloxy-tris(dimethylamino)phosphanium;hexafluorophosphate |
| SMILES | CN(C)[P+](N(C)C)(N(C)C)ON1C2=CC=CC=C2N=N1.F[P-](F)(F)(F)(F)F |
| Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
|---|---|---|---|---|---|---|---|---|---|
| Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
|
11443187
|
Thermo Scientific Alfa Aesar
A16140.03 |
1 g |
33.37 EUR
1g |
[resources not loaded] | |||||
|
11453187
|
Thermo Scientific Alfa Aesar
A16140.06 |
5 g |
79.50 EUR
5g |
[resources not loaded] | |||||
|
11463187
|
Thermo Scientific Alfa Aesar
A16140.14 |
25 g |
316.58 EUR
25g |
[resources not loaded] | |||||
Description
1H-Benzotriazol-1-yloxytris(dimethylamino)phosphonium hexafluorophosphate is used as a reagent for peptide coupling, lactonization, selective esterification, amidation of alfa amino acids without racemization and synthesis of magnolamide for antioxidative activity and catalyst for 9-acridinecaroboxamide derivative. It is also used as a precursor for the synthesis of phenyl esters of amino acids. It acts as a substitute for (Benzotriazol-1-yloxy)tris(dimethylamino)phosphonium hexafluorophosphate (BOP) reagent.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications1H-Benzotriazol-1-yloxytris(dimethylamino)phosphonium hexafluorophosphate is used as a reagent for peptide coupling, lactonization, selective esterification, amidation of alfa amino acids without racemization and synthesis of magnolamide for antioxidative activity and catalyst for 9-acridinecaroboxamide derivative. It is also used as a precursor for the synthesis of phenyl esters of amino acids. It acts as a substitute for (Benzotriazol-1-yloxy)tris(dimethylamino)phosphonium hexafluorophosphate (BOP) reagent.
Solubility
Soluble in methanol, acetone and dichloromethane. Insoluble in water.
Notes
Moisture and light sensitive. Incompatible with strong oxidizing agents. Store in a cool place. Keep the container tightly closed.
Chemical Identifiers
| 56602-33-6 | |
| 442.287 | |
| MGEVGECQZUIPSV-UHFFFAOYSA-N | |
| 151348 | |
| CN(C)[P+](N(C)C)(N(C)C)ON1C2=CC=CC=C2N=N1.F[P-](F)(F)(F)(F)F |
| C12H22F6N6OP2 | |
| MFCD00011948 | |
| bop reagent, 1h-benzo d 1,2,3 triazol-1-yl oxy tris dimethylamino phosphonium hexafluorophosphate v, castro's reagent, bop-reagent, benzotriazol-1-yloxytris dimethylamino-phosphonium hexafluorophosphate, ccris 2602, castros reagent, tri dimethylamino benzotriazol-1-yloxyphosphonium hexafluorophosphate, benzotriazol-1-yloxy tris dimethylamino phosphonium hexafluorophosphate, 1h-benzotriazol-1-yloxytris dimethylamino phosphonium hexafluorophosphate | |
| benzotriazol-1-yloxy-tris(dimethylamino)phosphanium;hexafluorophosphate |
Specifications
| 56602-33-6 | |
| C12H22F6N6OP2 | |
| UN1325 | |
| bop reagent, 1h-benzo d 1,2,3 triazol-1-yl oxy tris dimethylamino phosphonium hexafluorophosphate v, castro's reagent, bop-reagent, benzotriazol-1-yloxytris dimethylamino-phosphonium hexafluorophosphate, ccris 2602, castros reagent, tri dimethylamino benzotriazol-1-yloxyphosphonium hexafluorophosphate, benzotriazol-1-yloxy tris dimethylamino phosphonium hexafluorophosphate, 1h-benzotriazol-1-yloxytris dimethylamino phosphonium hexafluorophosphate | |
| CN(C)[P+](N(C)C)(N(C)C)ON1C2=CC=CC=C2N=N1.F[P-](F)(F)(F)(F)F | |
| 442.287 | |
| 442.29 | |
| 1H-Benzotriazol-1-yloxytris(dimethylamino)phosphonium hexafluorophosphate |
| ∼138°C (decomposition) | |
| MFCD00011948 | |
| 4287025 | |
| MGEVGECQZUIPSV-UHFFFAOYSA-N | |
| benzotriazol-1-yloxy-tris(dimethylamino)phosphanium;hexafluorophosphate | |
| 151348 | |
| 98% |
Safety and Handling
GHS H Statement
H228-H315-H319-H335
Flammable solid.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
GHS P Statement
P210-P261-P280-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Danger
missing translation for 'dotInformation' : Transport Hazard Class: 4.1; Packing Group: II; Proper Shipping Name: FLAMMABLE SOLIDS, ORGANIC, N.O.S.
Recommended Storage : 2° to 8°C
RUO – Research Use Only
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