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5-O-tert-Butyldimethylsilyl-2,3-O-isopropylidene-alpha,beta-D-ribofuranose, Thermo Scientific™
34.26 EUR - 93.23 EUR
Chemical Identifiers
CAS | 68703-51-5 |
---|---|
Molecular Formula | C14H28O5Si |
Molecular Weight (g/mol) | 304.458 |
MDL Number | MFCD01075716 |
InChI Key | JJLRGSYXWAKGJM-SGUBAKSOSA-N |
Synonym | 5-o-tert-butyldimethylsilyl-2,3-o-isopropylidene-d-ribose, 3as,4r,6r-6-tert-butyldimethylsilyl oxy methyl-2,2-dimethyl-tetrahydrofuro 3,4-d 1,3 dioxol-4-olShow More |
PubChem CID | 71314364 |
IUPAC Name | (3aS,4R,6R)-6-[[tert-butyl(dimethyl)silyl]oxymethyl]-2,2-dimethyl-3a,4,6,6a-tetrahydrofuro[3,4-d][1,3]dioxol-4-ol |
SMILES | CC1(OC2C(OC(C2O1)O)CO[Si](C)(C)C(C)(C)C)C |
Description
This Thermo Scientific brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific.
Applications5-O-tert-Butyldimethylsilyl-2,3-O-isopropylidene-α,β-D-ribofuranose is used as a starting material for the preparation of N-benzyl alfa-L-manno aminocyclopentitol , 4-deoxy-N-benzyl-alfa-L-manno aminocyclopentitol and N-benzyl 6,7-di-epi-trehalamine using stereoselective allylation. It is also used in oligosaccharides.
Solubility
Soluble in dichloromethane and ethyl acetate.
Notes
Incompatible with oxidizing agents.
Chemical Identifiers
68703-51-5 | |
304.458 | |
JJLRGSYXWAKGJM-SGUBAKSOSA-N | |
71314364 | |
CC1(OC2C(OC(C2O1)O)CO[Si](C)(C)C(C)(C)C)C |
C14H28O5Si | |
MFCD01075716 | |
5-o-tert-butyldimethylsilyl-2,3-o-isopropylidene-d-ribose, 3as,4r,6r-6-tert-butyldimethylsilyl oxy methyl-2,2-dimethyl-tetrahydrofuro 3,4-d 1,3 dioxol-4-olShow More | |
(3aS,4R,6R)-6-[[tert-butyl(dimethyl)silyl]oxymethyl]-2,2-dimethyl-3a,4,6,6a-tetrahydrofuro[3,4-d][1,3]dioxol-4-olShow More |
Specifications
68703-51-5 | |
C14H28O5Si | |
5-o-tert-butyldimethylsilyl-2,3-o-isopropylidene-d-ribose, 3as,4r,6r-6-tert-butyldimethylsilyl oxy methyl-2,2-dimethyl-tetrahydrofuro 3,4-d 1,3 dioxol-4-ol | |
JJLRGSYXWAKGJM-SGUBAKSOSA-N | |
CC1(OC2C(OC(C2O1)O)CO[Si](C)(C)C(C)(C)C)C | |
304.458 | |
304.46 |
50°C to 53°C | |
MFCD01075716 | |
Soluble in dichloromethane and ethyl acetate. | |
−13.3° (c=1 in Chloroform) | |
(3aS,4R,6R)-6-[[tert-butyl(dimethyl)silyl]oxymethyl]-2,2-dimethyl-3a,4,6,6a-tetrahydrofuro[3,4-d][1,3]dioxol-4-ol | |
71314364 | |
5-O-tert-Butyldimethylsilyl-2,3-O-isopropylidene-alpha,beta-D-ribofuranose |
Safety and Handling
missing translation for 'tsca' : No
Recommended Storage : Store at -20°C
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Product Title
5-O-tert-Butyldimethylsilyl-2,3-O-isopropylidene-alpha,beta-D-ribofuranose, Thermo Scientific™