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Allylmagnesium chloride, 1M in MeTHF, Thermo Scientific Chemicals
163.82 EUR - 664.31 EUR
Chemical Identifiers
| CAS | 2622-05-1 |
|---|---|
| Molecular Formula | C3H5ClMg |
| Molecular Weight (g/mol) | 100.83 |
| MDL Number | MFCD00000473 |
| InChI Key | PLYLAFITHJUEGX-UHFFFAOYSA-M |
| Synonym | allylmagnesium chloride, magnesium, chloro-2-propenyl, magnesium, chloro-2-propen-1-yl, chloro prop-2-en-1-yl magnesium, allylmagnesium chloride solution, 2.0 m in thf, sjpdadpprujp@, allylmagnesiumchloride, allyl magnesium chloride, allyl-magnesium chloride, 2-propenyl magnesium chloride |
| PubChem CID | 75804 |
| IUPAC Name | magnesium;prop-1-ene;chloride |
| SMILES | Cl[Mg]CC=C |
| Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
|---|---|---|---|---|---|---|---|---|---|
| Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
|
15478057
|
Thermo Scientific Alfa Aesar
H51170.AE |
100 mL |
163.82 EUR
100mL |
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|
15488057
|
Thermo Scientific Alfa Aesar
H51170.AP |
500 mL |
664.31 EUR
500mL |
Please sign in to purchase this item. Need a web account? Register with us today! | |||||
Description
Allylmagnesium chloride has been used in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5?-disubstituted hydantoins. It is also used as a reagent for the introduction of the allyl group.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsAllylmagnesium chloride has been used in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5′-disubstituted hydantoins. It is also used as a reagent for the introduction of the allyl group.
Solubility
It reacts violently with water.
Notes
Air & moisture sensitive. Stable under recommended storage conditions.
Chemical Identifiers
| 2622-05-1 | |
| 100.83 | |
| PLYLAFITHJUEGX-UHFFFAOYSA-M | |
| 75804 | |
| Cl[Mg]CC=C |
| C3H5ClMg | |
| MFCD00000473 | |
| allylmagnesium chloride, magnesium, chloro-2-propenyl, magnesium, chloro-2-propen-1-yl, chloro prop-2-en-1-yl magnesium, allylmagnesium chloride solution, 2.0 m in thf, sjpdadpprujp@, allylmagnesiumchloride, allyl magnesium chloride, allyl-magnesium chloride, 2-propenyl magnesium chloride | |
| magnesium;prop-1-ene;chloride |
Specifications
| 2622-05-1 | |
| CH2=CHCH2MgCl | |
| UN3399 | |
| allylmagnesium chloride, magnesium, chloro-2-propenyl, magnesium, chloro-2-propen-1-yl, chloro prop-2-en-1-yl magnesium, allylmagnesium chloride solution, 2.0 m in thf, sjpdadpprujp@, allylmagnesiumchloride, allyl magnesium chloride, allyl-magnesium chloride, 2-propenyl magnesium chloride | |
| PLYLAFITHJUEGX-UHFFFAOYSA-M | |
| magnesium;prop-1-ene;chloride | |
| 75804 | |
| 1M in MeTHF |
| C3H5ClMg | |
| MFCD00000473 | |
| Air and moisture sensitive | |
| It reacts violently with water. | |
| Cl[Mg]CC=C | |
| 100.83 | |
| 100.83 | |
| Allylmagnesium chloride |
Safety and Handling
GHS H Statement
H225-H261-H314-H318
Highly flammable liquid and vapor.
In contact with water releases flammable gas.
Causes severe skin burns and eye damage.
Causes serious eye damage.
P210-P223-P231+P232-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P335+P334-P363-P370+P378q-P501c
H225-H260-H302-H314-H335
missing translation for 'dotInformation' : Transport Hazard Class: 4.3; Packing Group: II; Proper Shipping Name: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE
missing translation for 'tsca' : Yes
Recommended Storage : Ambient temperatures
Product Identifier
Signal Word
Hazard Category
Hazard Statement
Precautionary Statement
Supplemental information
- Allylmagnesium chloride, 1M in MeTHF
Signal Word
- Danger
Hazard Category
- Acute toxicity Category 4
- Serious eye damage/eye irritation Category 1
- Flammable liquid Category 2
- Skin corrosion/irritation Category 1 B
- Substance which\, in contact with water\, emits flammable gases Category 1
Hazard Statement
- H225-Highly flammable liquid and vapour.
- H260-In contact with water releases flammable gases which may ignite spontaneously.
- H302-Harmful if swallowed.
- H314-Causes severe skin burns and eye damage.
- H318-Causes serious eye damage.
- EUH014-Reacts violently with water.
- EUH019-May form explosive peroxides.
Precautionary Statement
- P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
- P231+P232-Handle under inert gas. Protect from moisture.
- P280-Wear protective gloves/protective clothing/eye protection/face protection.
- P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
- P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
- P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P310-Immediately call a POISON CENTER/doctor/.
- P335+P334-Brush off loose particles from skin Immerse in cool water/wrap in wet bandages.
Supplemental information
- MIXTURE LIST-Contains : 2-Methyltetrahydrofuran, chloro-2-propenyl-magnesium
RUO – Research Use Only
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