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Allylpalladium(II) chloride dimer, Pd 56.0% min, Thermo Scientific Chemicals
65.02 EUR - 1017.06 EUR
Chemical Identifiers
| CAS | 12012-95-2 |
|---|---|
| Molecular Formula | C6H10Cl2Pd2 |
| Molecular Weight (g/mol) | 365.89 |
| MDL Number | MFCD00044874 |
| InChI Key | PENAXHPKEVTBLF-UHFFFAOYSA-L |
| Synonym | allylpalladium chloride dimer, bis allyl dichlorodipalladium, diallyldipalladium dichloride, palladium allyl chloride dimer, diallydichlorodipalladium, pi-allyl palladium chloride, allylpalladium ii chloride, bis chloro-pi-allylpalladium, allyl palladium chloride dimer, bis pi-allyl chloropalladium |
| PubChem CID | 61538 |
| IUPAC Name | chloropalladium(1+);prop-1-ene |
| SMILES | Cl[Pd].Cl[Pd].c:c:c.c:c:c |
| Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
|---|---|---|---|---|---|---|---|---|---|
| Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
|
11356707
|
Thermo Scientific Alfa Aesar
010005.01 |
0.25 g |
65.02 EUR
0.25g |
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|
11346707
|
Thermo Scientific Alfa Aesar
010005.03 |
1 g |
205.02 EUR
1g |
Please sign in to purchase this item. Need a web account? Register with us today! | |||||
|
11366707
|
Thermo Scientific Alfa Aesar
010005.06 |
5 g |
1017.06 EUR
5g |
Please sign in to purchase this item. Need a web account? Register with us today! | |||||
Description
Allylpalladium(II) chloride dimer is used as an important catalyst in Heck reaction. It reacts with cyclopentadienyl anion to give cyclopentadienyl allyl palladium. It acts as a precatalyst for asymmetric and cross-coupling catalysis. Further, it is used in the preparation of 1,4-diallyl-1,2-dihydroisoquinolines. It is also employed as a catalyst for greener Buchwald-Hartwig coupling reaction and involved in the synthesis of cationic palladium catalysts. In addition, it takes part in preparation of -heterocyclic carbene-palladium-eta3-allyl chloride complex, which is an efficient catalyst for the Suzuki-Miyaura cross-coupling reactions in synthetic chemistry.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Chemical Identifiers
| 12012-95-2 | |
| 365.89 | |
| PENAXHPKEVTBLF-UHFFFAOYSA-L | |
| 61538 | |
| Cl[Pd].Cl[Pd].c:c:c.c:c:c |
| C6H10Cl2Pd2 | |
| MFCD00044874 | |
| allylpalladium chloride dimer, bis allyl dichlorodipalladium, diallyldipalladium dichloride, palladium allyl chloride dimer, diallydichlorodipalladium, pi-allyl palladium chloride, allylpalladium ii chloride, bis chloro-pi-allylpalladium, allyl palladium chloride dimer, bis pi-allyl chloropalladium | |
| chloropalladium(1+);prop-1-ene |
Specifications
| 12012-95-2 | |
| Yellow | |
| MFCD00044874 | |
| Air and moisture sensitive | |
| Very soluble in dichloromethane and dichloroethane; Slightly soluble in toluene,insoluble in waterSoluble in chloroform,benzene,acetone and dichloromethane,dichloroethane and methanol; Slightly soluble in toluene; Insoluble in water. | |
| Cl[Pd].Cl[Pd].c:c:c.c:c:c | |
| 365.89 | |
| 365.85 | |
| Powder |
| 120°C (decomposition) | |
| C6H10Cl2Pd2 | |
| 4124623 | |
| allylpalladium chloride dimer, bis allyl dichlorodipalladium, diallyldipalladium dichloride, palladium allyl chloride dimer, diallydichlorodipalladium, pi-allyl palladium chloride, allylpalladium ii chloride, bis chloro-pi-allylpalladium, allyl palladium chloride dimer, bis pi-allyl chloropalladium | |
| PENAXHPKEVTBLF-UHFFFAOYSA-L | |
| chloropalladium(1+);prop-1-ene | |
| 61538 | |
| Pd 56.0% min. | |
| Allylpalladium(II) chloride dimer |
Safety and Handling
GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
P264b-P280-P302+P352-P305+P351+P338-P332+P313-P362
H315-H319
missing translation for 'einecsNumber' : 234-579-8
missing translation for 'rtecsNumber' : RT3510000
missing translation for 'tsca' : No
missing translation for 'storageNote' : 2°C to 8°C
Recommended Storage : Keep cold; Store under Nitrogen
Product Identifier
Signal Word
Hazard Category
Hazard Statement
Precautionary Statement
- Allylpalladium(II) chloride dimer
Signal Word
- Warning
Hazard Category
- Skin corrosion/irritation Category 2
- Serious eye damage/eye irritation Category 2
- Specific target organ toxicity Category 3
Hazard Statement
- H315-Causes skin irritation.
- H319-Causes serious eye irritation.
- H335-May cause respiratory irritation.
Precautionary Statement
- P261-Avoid breathing dust/fume/gas/mist/vapours/spray.
- P280-Wear protective gloves/protective clothing/eye protection/face protection.
- P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
- P405-Store locked up.
- P501-Dispose of contents/container to .
RUO – Research Use Only