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Bis(3,5-di-tert-butyl-4-methoxyphenyl)chlorophosphine, 94%, Thermo Scientific Chemicals Product Code.: 11485620
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Bis(3,5-di-tert-butyl-4-methoxyphenyl)chlorophosphine, 94%, Thermo Scientific Chemicals

Product Code. 11485620
5 g
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Quantity:
1 g
5 g
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Product Code. 11485620

Brand: Thermo Scientific Alfa Aesar H25882.06

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Description

It is used as a reactant for asymmetric hydrogenation with iridium catalysts, chemo selective reaction with deprotonated 2-hydoxy-3,3,N-trimethylbutanamide. It is also used as a reactant for synthesis of phosphine- containing amino acids and peptide-based catalyst ligands, nonracemic phosphine-containing amino acids for palladium- catalyzed asymmetric allylic substitution reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
It is used as a reactant for asymmetric hydrogenation with iridium catalysts, chemo selective reaction with deprotonated 2-hydoxy-3,3,N-trimethylbutanamide. It is also used as a reactant for synthesis of phosphine- containing amino acids and peptide-based catalyst ligands, nonracemic phosphine-containing amino acids for palladium- catalyzed asymmetric allylic substitution reactions.

Solubility
Reacts with water.

Notes
Air & moisture sensitive. Materials to avoid is oxidizing agents, bases.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 212713-08-1
Molecular Formula C30H46ClO2P
Molecular Weight (g/mol) 505.12
MDL Number MFCD08458881
InChI Key VOGHMZHRQUWLRE-UHFFFAOYSA-N
Synonym bis 3,5-di-tert-butyl-4-methoxyphenyl chlorophosphine, acmc-20alnq, chlorobis 3,5-di-tert-butyl-4-methoxyphenyl phosphane, chlorobis 3,5-di-tert-butyl-4-methoxyphenyl phosphine, bis 3,5-di-tert-butyl-4-methoxyphenyl phosphinous chloride, bis 3,5-bis 1,1-dimethylethyl-4-methoxyphenyl phosphinous chloride, phosphinous chloride,bis 3,5-bis 1,1-dimethylethyl-4-methoxyphenyl-9ciShow MoreShow Less
PubChem CID 53431072
IUPAC Name chloro-bis(3,5-ditert-butyl-4-methoxyphenyl)phosphane
SMILES CC(C)(C)C1=CC(=CC(=C1OC)C(C)(C)C)P(C2=CC(=C(C(=C2)C(C)(C)C)OC)C(C)(C)C)Cl

Specifications

Quantity 5 g
UN Number UN3261
Sensitivity Air and moisture sensitive
Solubility Information Reacts with water.
Formula Weight 505.13
Percent Purity 94%
Chemical Name or Material Bis(3,5-di-tert-butyl-4-methoxyphenyl)chlorophosphine

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Lot Number Certificate Type Date Catalog Number
Lot Number10156603 Certificate TypeCertificate of Analysis Date23/11/2021 Catalog NumberH25882.03,H25882.06
Lot Number10231250 Certificate TypeCertificate of Analysis Date23/11/2021 Catalog NumberH25882.03,H25882.06
Lot Number10159591 Certificate TypeCertificate of Analysis Date23/11/2021 Catalog NumberH25882.03,H25882.06
Lot Number10156604 Certificate TypeCertificate of Analysis Date23/11/2021 Catalog NumberH25882.03,H25882.06
Lot Number10214340 Certificate TypeCertificate of Analysis Date23/11/2021 Catalog NumberH25882.03,H25882.06

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