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Borane-dimethyl sulfide complex, 94%, Thermo Scientific Chemicals

Product Code. 11456750
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Quantity:
25 mL
100 mL

Borane- dimethyl sulfide is used for hydroboration and reduction reactions. It is used in the reduction of aldehydes, ketones, epoxides and carboxylic acids to give corresponding alcohols. It is also involved in the Corey-Itsuno reduction. It acts as an intermediate in the preparation of highly pure semiconductor. It is also employed as a rocket propellant.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Borane- dimethyl sulfide is used for hydroboration and reduction reactions. It is used in the reduction of aldehydes, ketones, epoxides and carboxylic acids to give corresponding alcohols. It is also involved in the Corey-Itsuno reduction. It acts as an intermediate in the preparation of highly pure semiconductor. It is also employed as a rocket propellant.

Solubility
Miscible with ethyl ether, dichloromethane, benzene, xylene, hexane, diglyme, dimethyl ether, ethyl acetate, toluene, methylene chloride and other aprotic solvents.

Notes
Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Store in a cool place. Incompatible with acids, water, alcohols, bromine, acid anhydrides, acid chlorides and oxidizing agents.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 13292-87-0
Molecular Formula C2H9BS
Molecular Weight (g/mol) 75.96
MDL Number MFCD00013189
InChI Key RMHDLBZYPISZOI-UHFFFAOYSA-N
Synonym dimethyl sulfide borane, borane-methyl sulfide complex, borane dimethyl sulfide complex, borane-dimethyl sulfide, dimethyl sulfideborane, dimethyl sulfide trihydroboron, borane-dimethyl sulfide complex, borane methylsulfide, borane dimethylsulfide, borane dms
PubChem CID 9833925
IUPAC Name boron;methylsulfanylmethane
SMILES B.CSC

Specifications

Melting Point -38°C
Density 0.801
Boiling Point ∼44°C (decomposition)
Flash Point −1°C (30°F)
Linear Formula (CH3)2S·BH3
Refractive Index 1.457
Quantity 100 mL
UN Number UN2924
Beilstein 3663489
Sensitivity Air and moisture sensitive
Solubility Information Miscible with ethyl ether,dichloromethane,benzene,xylene,hexane,diglyme,dimethyl ether,ethyl acetate,toluene,methylene chloride and other aprotic solvents.
Formula Weight 75.97
Percent Purity 94%
Chemical Name or Material Borane-dimethyl sulfide complex
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Signal Word
  • Danger
Hazard Category
  • Acute toxicity Category 3
  • LONG-TERM AQUATIC HAZARD Chronic 3
  • Serious eye damage/eye irritation Category 1
  • Flammable liquid Category 2
  • Reproductive toxicity Category 1B
  • Skin corrosion/irritation Category 2
  • Substance which\, in contact with water\, emits flammable gases Category 1
Hazard Statement
  • H225-Highly flammable liquid and vapour.
  • H260-In contact with water releases flammable gases which may ignite spontaneously.
  • H301-Toxic if swallowed.
  • H311-Toxic in contact with skin.
  • H315-Causes skin irritation.
  • H318-Causes serious eye damage.
  • H360FD-May damage fertility. May damage the unborn child.
  • H412-Harmful to aquatic life with long lasting effects.
  • EUH014-Reacts violently with water.
Precautionary Statement
  • P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  • P231+P232-Handle under inert gas. Protect from moisture.
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
  • P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
  • P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P310-Immediately call a POISON CENTER/doctor/.

RUO – Research Use Only

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