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1H-Benzotriazol-1-yloxytris(dimethylamino)phosphonium hexafluorophosphate, 98%, Thermo Scientific Chemicals Product Code.: 11453187
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1H-Benzotriazol-1-yloxytris(dimethylamino)phosphonium hexafluorophosphate, 98%, Thermo Scientific Chemicals

Product Code. 11453187
5 g
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Quantity:
1 g
5 g
25 g
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Product Code. 11453187

Brand: Thermo Scientific Alfa Aesar A16140.06

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Description

1H-Benzotriazol-1-yloxytris(dimethylamino)phosphonium hexafluorophosphate is used as a reagent for peptide coupling, lactonization, selective esterification, amidation of alfa amino acids without racemization and synthesis of magnolamide for antioxidative activity and catalyst for 9-acridinecaroboxamide derivative. It is also used as a precursor for the synthesis of phenyl esters of amino acids. It acts as a substitute for (Benzotriazol-1-yloxy)tris(dimethylamino)phosphonium hexafluorophosphate (BOP) reagent.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1H-Benzotriazol-1-yloxytris(dimethylamino)phosphonium hexafluorophosphate is used as a reagent for peptide coupling, lactonization, selective esterification, amidation of alfa amino acids without racemization and synthesis of magnolamide for antioxidative activity and catalyst for 9-acridinecaroboxamide derivative. It is also used as a precursor for the synthesis of phenyl esters of amino acids. It acts as a substitute for (Benzotriazol-1-yloxy)tris(dimethylamino)phosphonium hexafluorophosphate (BOP) reagent.

Solubility
Soluble in methanol, acetone and dichloromethane. Insoluble in water.

Notes
Moisture and light sensitive. Incompatible with strong oxidizing agents. Store in a cool place. Keep the container tightly closed.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 56602-33-6
Molecular Formula C12H22F6N6OP2
Molecular Weight (g/mol) 442.287
MDL Number MFCD00011948
InChI Key MGEVGECQZUIPSV-UHFFFAOYSA-N
Synonym bop reagent, 1h-benzo d 1,2,3 triazol-1-yl oxy tris dimethylamino phosphonium hexafluorophosphate v, castro's reagent, bop-reagent, benzotriazol-1-yloxytris dimethylamino-phosphonium hexafluorophosphate, ccris 2602, castros reagent, tri dimethylamino benzotriazol-1-yloxyphosphonium hexafluorophosphate, benzotriazol-1-yloxy tris dimethylamino phosphonium hexafluorophosphate, 1h-benzotriazol-1-yloxytris dimethylamino phosphonium hexafluorophosphateShow MoreShow Less
PubChem CID 151348
IUPAC Name benzotriazol-1-yloxy-tris(dimethylamino)phosphanium;hexafluorophosphate
SMILES CN(C)[P+](N(C)C)(N(C)C)ON1C2=CC=CC=C2N=N1.F[P-](F)(F)(F)(F)F

Specifications

Melting Point ∼138°C (decomposition)
Quantity 5 g
UN Number UN1325
Beilstein 4287025
Sensitivity Light and moisture sensitive
Solubility Information Soluble in methanol,acetone and dichloromethane. Insoluble in water.
Formula Weight 442.29
Percent Purity 98%
Chemical Name or Material 1H-Benzotriazol-1-yloxytris(dimethylamino)phosphonium hexafluorophosphate

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5 results found
Lot Number Certificate Type Date Catalog Number
Lot Number10220796 Certificate TypeCertificate of Analysis Date12/04/2024 Catalog NumberA16140.14,A16140.06
Lot Number10212649 Certificate TypeCertificate of Analysis Date25/04/2023 Catalog NumberA16140.14,A16140.06
Lot NumberH02P09 Certificate TypeCertificate of Analysis Date23/11/2021 Catalog NumberA16140.14,A16140.06
Lot NumberF5812A Certificate TypeCertificate of Analysis Date23/11/2021 Catalog NumberA16140.14,A16140.06
Lot NumberF5812B Certificate TypeCertificate of Analysis Date23/11/2021 Catalog NumberA16140.14,A16140.06

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