missing translation for 'onlineSavingsMsg'
Learn More
1H-Benzotriazol-1-yloxytris(dimethylamino)phosphonium hexafluorophosphate, 98%, Thermo Scientific Chemicals Product Code.: 11453187
  1. Home
  2. Products
  3. Chemicals
  4. Organic compounds
  5. Organoheterocyclic compounds
  6. Azoles
  7. Triazoles
  8. 1H-Benzotriazol-1-yloxytris(dimethylamino)phosphonium hexafluorophosphate, 98%, Thermo Scientific Chemicals
SDS

1H-Benzotriazol-1-yloxytris(dimethylamino)phosphonium hexafluorophosphate, 98%, Thermo Scientific Chemicals

Product Code. 11453187
5 g
Click to view available options
Quantity:
1 g
5 g
25 g
This item is not returnable. View return policy

Product Code. 11453187

Brand: Thermo Scientific Alfa Aesar A16140.06

Request Bulk or Custom Format

Please to purchase this item. Need a web account? Register with us today!

Explore more special offers
This item is not returnable. View return policy

Description

1H-Benzotriazol-1-yloxytris(dimethylamino)phosphonium hexafluorophosphate is used as a reagent for peptide coupling, lactonization, selective esterification, amidation of alfa amino acids without racemization and synthesis of magnolamide for antioxidative activity and catalyst for 9-acridinecaroboxamide derivative. It is also used as a precursor for the synthesis of phenyl esters of amino acids. It acts as a substitute for (Benzotriazol-1-yloxy)tris(dimethylamino)phosphonium hexafluorophosphate (BOP) reagent.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1H-Benzotriazol-1-yloxytris(dimethylamino)phosphonium hexafluorophosphate is used as a reagent for peptide coupling, lactonization, selective esterification, amidation of alfa amino acids without racemization and synthesis of magnolamide for antioxidative activity and catalyst for 9-acridinecaroboxamide derivative. It is also used as a precursor for the synthesis of phenyl esters of amino acids. It acts as a substitute for (Benzotriazol-1-yloxy)tris(dimethylamino)phosphonium hexafluorophosphate (BOP) reagent.

Solubility
Soluble in methanol, acetone and dichloromethane. Insoluble in water.

Notes
Moisture and light sensitive. Incompatible with strong oxidizing agents. Store in a cool place. Keep the container tightly closed.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 56602-33-6
Molecular Formula C12H22F6N6OP2
Molecular Weight (g/mol) 442.287
MDL Number MFCD00011948
InChI Key MGEVGECQZUIPSV-UHFFFAOYSA-N
Synonym bop reagent, 1h-benzo d 1,2,3 triazol-1-yl oxy tris dimethylamino phosphonium hexafluorophosphate v, castro's reagent, bop-reagent, benzotriazol-1-yloxytris dimethylamino-phosphonium hexafluorophosphate, ccris 2602, castros reagent, tri dimethylamino benzotriazol-1-yloxyphosphonium hexafluorophosphate, benzotriazol-1-yloxy tris dimethylamino phosphonium hexafluorophosphate, 1h-benzotriazol-1-yloxytris dimethylamino phosphonium hexafluorophosphate
PubChem CID 151348
IUPAC Name benzotriazol-1-yloxy-tris(dimethylamino)phosphanium;hexafluorophosphate
SMILES CN(C)[P+](N(C)C)(N(C)C)ON1C2=CC=CC=C2N=N1.F[P-](F)(F)(F)(F)F

Specifications

Melting Point ∼138°C (decomposition)
Quantity 5 g
UN Number UN1325
Beilstein 4287025
Sensitivity Light and moisture sensitive
Solubility Information Soluble in methanol,acetone and dichloromethane. Insoluble in water.
Formula Weight 442.29
Percent Purity 98%
Chemical Name or Material 1H-Benzotriazol-1-yloxytris(dimethylamino)phosphonium hexafluorophosphate

Certificates

Certificates

A lot number is required to show results for certificates. To find your lot number on previous orders use our order status area.

5 results found
Lot Number Certificate Type Date Catalog Number
Lot Number10220796 Certificate TypeCertificate of Analysis Date12/04/2024 Catalog NumberA16140.14,A16140.06
Lot Number10212649 Certificate TypeCertificate of Analysis Date25/04/2023 Catalog NumberA16140.14,A16140.06
Lot NumberH02P09 Certificate TypeCertificate of Analysis Date23/11/2021 Catalog NumberA16140.14,A16140.06
Lot NumberF5812A Certificate TypeCertificate of Analysis Date23/11/2021 Catalog NumberA16140.14,A16140.06
Lot NumberF5812B Certificate TypeCertificate of Analysis Date23/11/2021 Catalog NumberA16140.14,A16140.06

RUO – Research Use Only

Product Content Correction

Your input is important to us. Please complete this form to provide feedback related to the content on this product.

Product Title
1H-Benzotriazol-1-yloxytris(dimethylamino)phosphonium hexafluorophosphate, 98%, Thermo Scientific Chemicals >

By clicking Submit, you acknowledge that you may be contacted by Fisher Scientific in regards to the feedback you have provided in this form. We will not share your information for any other purposes. All contact information provided shall also be maintained in accordance with our Privacy Policy.

Thank You! Your feedback has been submitted. Fisher Scientific is always working to improve our content for you. We appreciate your feedback.