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Borane-dimethyl sulfide complex, 94%, Thermo Scientific Chemicals
53.16 EUR - 203.01 EUR
Chemical Identifiers
| CAS | 13292-87-0 |
|---|---|
| Molecular Formula | C2H9BS |
| Molecular Weight (g/mol) | 75.96 |
| MDL Number | MFCD00013189 |
| InChI Key | RMHDLBZYPISZOI-UHFFFAOYSA-N |
| Synonym | dimethyl sulfide borane, borane-methyl sulfide complex, borane dimethyl sulfide complex, borane-dimethyl sulfide, dimethyl sulfideborane, dimethyl sulfide trihydroboron, borane-dimethyl sulfide complex, borane methylsulfide, borane dimethylsulfide, borane dms |
| PubChem CID | 9833925 |
| IUPAC Name | boron;methylsulfanylmethane |
| SMILES | B.CSC |
| Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
|---|---|---|---|---|---|---|---|---|---|
| Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
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11446750
|
Thermo Scientific Alfa Aesar
L07705.AC |
25 mL |
53.16 EUR
25mL |
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|
11456750
|
Thermo Scientific Alfa Aesar
L07705.AE |
100 mL |
203.01 EUR
100mL |
Please sign in to purchase this item. Need a web account? Register with us today! | |||||
Description
Borane- dimethyl sulfide is used for hydroboration and reduction reactions. It is used in the reduction of aldehydes, ketones, epoxides and carboxylic acids to give corresponding alcohols. It is also involved in the Corey-Itsuno reduction. It acts as an intermediate in the preparation of highly pure semiconductor. It is also employed as a rocket propellant.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsBorane- dimethyl sulfide is used for hydroboration and reduction reactions. It is used in the reduction of aldehydes, ketones, epoxides and carboxylic acids to give corresponding alcohols. It is also involved in the Corey-Itsuno reduction. It acts as an intermediate in the preparation of highly pure semiconductor. It is also employed as a rocket propellant.
Solubility
Miscible with ethyl ether, dichloromethane, benzene, xylene, hexane, diglyme, dimethyl ether, ethyl acetate, toluene, methylene chloride and other aprotic solvents.
Notes
Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Store in a cool place. Incompatible with acids, water, alcohols, bromine, acid anhydrides, acid chlorides and oxidizing agents.
Chemical Identifiers
| 13292-87-0 | |
| 75.96 | |
| RMHDLBZYPISZOI-UHFFFAOYSA-N | |
| 9833925 | |
| B.CSC |
| C2H9BS | |
| MFCD00013189 | |
| dimethyl sulfide borane, borane-methyl sulfide complex, borane dimethyl sulfide complex, borane-dimethyl sulfide, dimethyl sulfideborane, dimethyl sulfide trihydroboron, borane-dimethyl sulfide complex, borane methylsulfide, borane dimethylsulfide, borane dms | |
| boron;methylsulfanylmethane |
Specifications
| 13292-87-0 | |
| 0.801 | |
| −1°C (30°F) | |
| (CH3)2S·BH3 | |
| MFCD00013189 | |
| 3663489 | |
| dimethyl sulfide borane, borane-methyl sulfide complex, borane dimethyl sulfide complex, borane-dimethyl sulfide, dimethyl sulfideborane, dimethyl sulfide trihydroboron, borane-dimethyl sulfide complex, borane methylsulfide, borane dimethylsulfide, borane dms | |
| RMHDLBZYPISZOI-UHFFFAOYSA-N | |
| boron;methylsulfanylmethane | |
| 9833925 | |
| 94% |
| -38°C | |
| ∼44°C (decomposition) | |
| C2H9BS | |
| 1.457 | |
| UN2924 | |
| Air and moisture sensitive | |
| Miscible with ethyl ether,dichloromethane,benzene,xylene,hexane,diglyme,dimethyl ether,ethyl acetate,toluene,methylene chloride and other aprotic solvents. | |
| B.CSC | |
| 75.96 | |
| 75.97 | |
| Borane-dimethyl sulfide complex |
Safety and Handling
GHS H Statement
H225-H260-H300-H314-H318-H335
Highly flammable liquid and vapor.
In contact with water releases flammable gases which may ignite spontaneously.
Fatal if swallowed.
Causes severe skin burns and eye damage.
Causes serious eye damage.
May cause respiratory irritation.
P210-P223-P231+P232-P233-P240-P241-P242-P243-P264b-P270-P280-P301+P310-P303+P361+P353-P305+P351+P338-P310-P330-P332+P313-P335+P334-P363-P370+P378q-P501c
H225-H260-H301-H315-H318
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missing translation for 'rtecsNumber' : PV5080000
missing translation for 'tsca' : Yes
Recommended Storage : Keep cold; Store under Argon
Signal Word
Hazard Category
Hazard Statement
Precautionary Statement
- Danger
Hazard Category
- Acute toxicity Category 3
- LONG-TERM AQUATIC HAZARD Chronic 3
- Serious eye damage/eye irritation Category 1
- Flammable liquid Category 2
- Reproductive toxicity Category 1B
- Skin corrosion/irritation Category 2
- Substance which\, in contact with water\, emits flammable gases Category 1
Hazard Statement
- H225-Highly flammable liquid and vapour.
- H260-In contact with water releases flammable gases which may ignite spontaneously.
- H301-Toxic if swallowed.
- H311-Toxic in contact with skin.
- H315-Causes skin irritation.
- H318-Causes serious eye damage.
- H360FD-May damage fertility. May damage the unborn child.
- H412-Harmful to aquatic life with long lasting effects.
- EUH014-Reacts violently with water.
Precautionary Statement
- P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
- P231+P232-Handle under inert gas. Protect from moisture.
- P280-Wear protective gloves/protective clothing/eye protection/face protection.
- P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
- P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
- P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P310-Immediately call a POISON CENTER/doctor/.
RUO – Research Use Only